Submissions from 2021
Preparation, Properties and Crystal Structure of syn-Isomer of 2,6-Dichlorophenyl-cyanoxime, H(2,6-diCl-PhCO): Potent Carbonyl Reductase Inhibitor, Seth Adu Amankrah, Oleksandr Hietsoi, Sergiy Tyukhtenko, Nikolay N. Gerasimchuk, and Henry Charlier
Ternary alkali ion thiogallates, A5GaS4(A = Li and Na), with isolated tetrahedral building units and their ionic conductivities, Srikanth Balijapelly, Prashanth Sandineni, Amit Adhikary, Nikolay N. Gerasimchuk, Aleksandr V. Chernatynskiy, and Amitava Choudhury
High Sodium-Ion Conductivity in Interlocked Quaternary Chalcogenides Built with Supertetrahedral Building Units, Srikanth Balijapelly, Qi Zhang, Prashanth Sandineni, Amit Adhikary, Sudip Mohapatra, Santhoshkumar Sundaramoorthy, Nikolay N. Gerasimchuk, Aleksandr V. Chernatynskiy, and Amitava Choudhury
Conformational control through co-operative nonconventional C - H-N hydrogen bonds, Eric Bosch, Nathan P. Bowling, and Shalisa M. Oburn
Arylethynyl Helices Supported by π-Stacking and Halogen Bonding, Nathan P. Bowling, Erin D. Speetzen, and Eric Bosch
Controlling topology within halogen-bonded networks by varying the regiochemistry of the cyclobutane-based nodes, Taylor J. Dunning, Daniel K. Unruh, Eric Bosch, and Ryan H. Groeneman
Verification of the neural network training process for spectrum-based chemical substructure prediction using metamorphic testing, Joshua D. Ellis, Razib Iqbal, and Keiichi Yoshimatsu
New Solids in As-O-Mo, As(P)-O-Mo(W) and As(P)-O-Nb(W) Systems That Exhibit Nonlinear Optical Properties, Nikolay N. Gerasimchuk, Lauri Kivijarvi, Bruce Noll, Meriem Goudjil, Soma Khanra, Yu Ping, Miles Pearson, and Frank Röminger
Tuning π-Acceptor/σ-Donor Ratio of the 2-Isocyanoazulene Ligand: Non-Fluorinated Rival of Pentafluorophenyl Isocyanide and Trifluorovinyl Isocyanide Discovered, Mason D. Hart, John J. Meyers, Zachary A. Wood, Toshinori Nakakita, Jason C. Applegate, Nathan R. Erickson, Nikolay N. Gerasimchuk, and Mikhail V. Barybin
Foliar application of nanoparticles: Mechanisms of absorption, transfer, and multiple impacts, Jie Hong, Chao Wang, Dane C. Wagner, Jorge L. Gardea-Torresdey, Feng He, and Cyren M. Rico
Centrosymmetric or Noncentrosymmetric? Transition Metals Talking in K2TGe3S8(T = Co, Fe), Bingheng Ji, Krishna Pandey, Colin P. Harmer, Fei Wang, Kui Wu, Jin Hu, and Jian Wang
The γ-Brass Type Cu–rich Complex Intermetallic Phase Cu41Sn11: Structure and Electrochemical Study, Samiran Misra, Debanjana Pahari, Souvik Giri, Fei Wang, Sreeraj Puravankara, and Partha P. Jana
Giant Topological Hall Effect in Centrosymmetric Tetragonal Mn2-xZnxSb, Md Rafique Un Nabi; Aaron Wegner; Fei Wang; Yanglin Zhu; Yingdong Guan; Arash Fereidouni; Krishna Pandey; Rabindra Basnet; Gokul Acharya; and For complete list of authors, see publisher's website.
Iodoperchlorobenzene acts as a dual halogen-bond donor to template a [2 + 2] cycloaddition reaction within an organic co-crystal, Nicole M. Shapiro, Eric Bosch, Daniel K. Unruh, Herman R. Krueger, and Ryan H. Groeneman
Single-Base Lesions and Mismatches Alter the Backbone Conformational Dynamics in DNA, M. N. Westwood, K. D. Ljunggren, Benjamin Boyd, Jaclyn Becker, Tammy J. Dwyer, and Gary A. Meints
Quasi-layered Crystal Structure Coupled with Point Defects Leading to Ultralow Lattice Thermal Conductivity in n-Type Cu2.83Bi10Se16, Zhengyang Ye, Wanyue Peng, Fei Wang, Ashiwini Balodhi, Rabindra Basnet, Jin Hu, Alexandra Zevalkink, and Jian Wang
Metal-Free Polymer-Based Affinity Medium for Selective Purification of His6-Tagged Proteins, Keiichi Yoshimatsu; Krista R. Fruehauf; Quanhong Zhu; Adam Weisman; Jun Fan; Min Xue; John M. Beierle; Paul E. Rose; Jennifer Aral; and For complete list of authors, see publisher's website.
Submissions from 2020
Unusual Atmospheric Water Trapping and Water Induced Reversible Restacking of 2D Gallium Sulfide Layers in NaGaS2Formed by Supertetrahedral Building Unit, Amit Adhikary, Hooman Yaghoobnejad Asl, Prashanth Sandineni, Srikanth Balijapelly, Sudip Mohapatra, Sajal Khatua, Sanjit Konar, Nikolay Gerasimchuk, Aleksandr V. Chernatynskiy, and Amitava Choudhury
Crystal structure and photoreactivity of a halogen-bonded cocrystal based upon 1,2-diiodoperchlorobenzene and 1,2-bis(pyridin-4-yl)ethylene, Eric Bosch, Jessica D. Battle, and Ryan H. Groeneman
Cooperative Strong Charge Assisted N-H---O Hydrogen Bonding and Weaker Nonconventional C-H---N Hydrogen Bonding in the Formation of Extended Hydrogen Bonded Networks with 2,3,5,6-tetrafuorobenzoic acid, Eric Bosch and Nathan P. Bowling
Search for the shortest intermetallic Tl—Tl contacts: Synthesis and characterization of Thallium(I) coordination polymers with several mono- and bis-cyanoximes, Scott Curtis, Brett Lottes, Daniel Robertson, Sergey V. Lindeman, and Nikolay Gerasimchuk
New in vitro highly cytotoxic platinum and palladium cyanoximates with minimal side effects in vivo, Stephanie D. Dannen; Lauren Cornelison; Paul Durham; John E. Morley; Kiana Shahverdi; Junwei Du; Haiying Zhou; Leland C. Sudlow; Nikolay Gerasimchuk; and For complete list of authors, see publisher's website.
Crystal Structures, Superconducting Properties, and the Coloring Problem in ReAlSi and ReGaSi, Victoria Decocq, Xin Gui, Alec Neeson, Weiwei Xie, Thomas Heitmann, and Fei Wang
A new approach for IR spectra matching using normalized local change, Joshua D. Ellis, Razib Iqbal, and Keiichi Yoshimatsu
Unusual Four-Membered Metallocycles in Complexes of Main Group III Metals, N. Gerasimchuk
Incorporating Ester Functionality within a Solid-State [2 + 2] Cycloaddition Reaction Based Upon Halogen Bonding Interactions, Samantha J. Kruse, Eric Bosch, Fayeshun Brown, and Ryan H. Groeneman
Synthesis, crystal structure, and thermal behavior of a diiron toluenethiolate complex with triphenylphosphine coligand, Jacob A. Martinez, Nikolay N. Gerasimchuk, and Charles A. Mebi
Macrocyclic tetranuclear double-butterfly Fe/S carbonyl clusters as [FeFe]-hydrogenase models, Charles A. Mebi and Nikolay N. Gerasimchuk
Unusual crystallographic ordering of two neighbouring elements - Cd and In in Cd2Cu3In, the first example in ternary Laves phase, S. Misra, B. Koley, S. Mahato, Fei Wang, and Partha P. Jana
Chemical substitution of Zn in the structure of ordered Cu6Zn2Sb2: A structural and theoretical study, S. Misra, S. Mallick, B. Koley, Fei Wang, S. Chatterjee, and Partha P. Jana
Planochromism of cyanoxime anions: Computational and mechanistic studies in solid state and solutions, Jeffrey Morton, Richard Dennison, Victor Nemykin, and Nikolay Gerasimchuk
Synthesis of 4-[(2-imidazylethynyl)]-5-(2-pyridylethynyl)veratrole and characterization of the coordination complexes with silver(I) and palladium(II), Chideraa I. Nwachukwu and Eric Bosch
Ditopic halogen bonding with bipyrimidines and activated pyrimidines, Chideraa I. Nwachukwu, Leanna J. Patton, Nathan P. Bowling, and Eric Bosch
Effect of vortex-induced physical stress on fluorescent properties of dye-containing poly(ethylene glycol)-block-poly(lactic acid) micelles, Tyler L. Odom, Jacob R. Blankenship, Giselle Campos, Devin C. Mart, Wenyan Liu, Risheng Wang, and Keiichi Yoshimatsu
Synthesis and Characterization of Anionic Lanthanide(III) Complexes with a Bidentate Sulfonylamidophosphate (SAPh) Ligand, Iryna Olyshevets, Nataliia Kariaka, Kateryna Znovjyak, Nikolay Gerasimchuk, Sergey Lindeman, Sergii Smola, Maksym Seredyuk, Tetiana Yu Sliva, and Vladimir M. Amirkhanov
Magneto-luminescent zinc/iron oxide core-shell nanoparticles with tunable magnetic properties, M. Reaz, Ariful Haque, D. M. Cornelison, A. Wanekaya, R. Delong, and K. Ghosh
Wheat exposure to cerium oxide nanoparticles over three generations reveals transmissible changes in nutrition, biochemical pools, and response to soil N, Cyren Rico, Oluwasegun Abolade, Dane Wagner, Brett Lottes, Justin Rodriguez, Richard Biagioni, and Christian P. Andersen
Metabolomics of wheat grains generationally-exposed to cerium oxide nanoparticles, Cyren Rico, Dane Wagner, Oluwasegun Michael Abolade, Brett Lottes, and Kameron Coates
Application of a tetrapyrimidyl cyclobutane synthesized in the organic solid state: A halogen-bonded supramolecular ladder, Michael A. Sinnwell, Carlos L. Santana, Eric Bosch, Leonard R. MacGillivray, and Ryan H. Groeneman
Submissions from 2019
3D Printed NMR Spectra: From 1D and 2D Acquisition to 3D Visualization, Michael Bakker, Ben Boyd, and Gary A. Meints
Construction by De-construction, Gautam Bhattacharyya
Crystal structure of the co-crystal salt 2-amino-6-bromopyridinium 2,3,5,6-tetrafluorobenzoate, Eric Bosch
Supramolecular Polymer Formation Featuring Cooperative Halogen Bonding and Nonconventional sp2-CH···N Hydrogen Bonding, Eric Bosch and Nathan P. Bowling
Infinite and discrete halogen bonded assemblies based upon 1,2-bis(iodoethynyl)benzene, Eric Bosch, Samantha J. Kruse, and Ryan H. Groeneman
Role of π-π Stacking and Halogen Bonding by 1,4-Diiodoperchlorobenzene to Organize the Solid State to Achieve a [2 + 2] Cycloaddition Reaction, Eric Bosch, Samantha J. Kruse, Herman R. Krueger Jr., and Ryan H. Groeneman
Regioselective [2 + 2] cycloaddition reaction within a pair of polymorphic co-crystals based upon halogen bonding interactions, Eric Bosch, Samantha J. Kruse, Eric W. Reinheimer, Nigam P. Rath, and Ryan H. Groeneman
TMI (Too much information)! Effects of given information on organic chemistry students' approaches to solving mechanism tasks, Victoria DeCocq and Gautam Bhattacharyya
New Insights into the Interactions of a DNA Oligonucleotide with mPEGylated-PAMAM by Circular Dichroism and Solution NMR, Xiaozheng Dou, Gary A. Meints, and Reza Sedaghat-Herati
In situ synthesis, stabilization and activity of protein-modified gold nanoparticles for biological applications, Celia Garcia-Hernandez, Allison K. Freese, Maria L. Rodriguez-Mendez, and Adam K. Wanekaya
Chemistry and applications of cyanoximes and their metal complexes, Nikolay Gerasimchuk
Effects of dynamic pedal motion and static disorder on thermal expansion within halogen-bonded co-crystals, Navkiran Juneja, Daniel K. Unruh, Eric Bosch, Ryan H. Groeneman, and Kristin M. Hutchins
Nanomedicine-assisted combination therapy of NSCLC: New platinum-based anticancer drug synergizes the therapeutic efficacy of ganetespib, Jyothi Kallu, Tuhina Banerjee, Shoukath Sulthana, Saloni Darji, Ryan Higginbotham, Christina Fletcher, Nikolay Gerasimchuk, and Santimukul Santra
Polymeric composites with silver (I) cyanoximates inhibit biofilm formation of gram-positive and gram-negative bacteria, S. R. Lotlikar, E. Gallaway, T. Grant, S. Popis, M. Whited, M. Guragain, R. Rogers, S. Hamilton, N. G. Gerasimchuk, and M. A. Patrauchan
Triple-Pnictogen Bonding as a Tool for Supramolecular Assembly, Shiva Moaven, Miranda C. Andrews, Thomas J. Polaske, Brian M. Karl, Daniel K. Unruh, Eric Bosch, Nathan Bowling, and Anthony F. Cozzolino
New Route to Polynuclear Ni(II) and Cu(II) Complexes with Bridging Oxime Groups That Are Inaccessible by Conventional Preparations, Adedamola A. Opalade, Carlos J. Gomez-Garcia, and Nikolay Gerasimchuk
Geochemical Fractionation of Stream Sediments Impacted by Pb-Zn Mining Wastes: Missouri, USA, Miles A. Pearson, Richard N. Biagioni, and Melida Gutierrez
Soft chemical routes to electrochemically active iron phosphates, Prashanth Sandineni, Hooman Yaghoobnejad Asl, Nikolay Gerasimchuk, Kartik Ghosh, and Amitava Choudhury
X-ray structure of the direct electron transfer-type FAD glucose dehydrogenase catalytic subunit complexed with a hitchhiker protein, Hiromi Yoshida, Katsuhiro Kojima, Masaki Shiota, Keiichi Yoshimatsu, Tomohiko Yamazaki, Stefano Ferri, Wakako Tsugawa, Shigehiro Kamitori, and Koji Sode
Submissions from 2018
The Mystery of the AuIn 1:1 Phase and Its Incommensurate Structural Variations, Laura C. Folkers, Arkadiy Simonov, Fei Wang, and Sven Lidin
An overview of nitrate sources and operating processes in arid and semiarid aquifer systems, Melida Gutierrez, Richard N. Biagioni, Ma Teresa Alarcon-Herrera, and Bertha A. Rivas-Lucero
Cyclic tetranuclear iron-carbonyl complex containing thiobisbenzenethiolate ligands: Synthesis and structural characterization, Shakeena L. Johnson, Nikolay N. Gerasimchuk, and Charles Mebi
Crystal and electronic structure of a hexacarbonyldiiron cluster tethered to naphthalene-2-thiolate ligands, C. Mebi, N. Gerasimchuk, and J. Lcbrecque
Synthesis and characterization of one, two and three-dimensional Cu(I) polymers supported by bipyridylamide ligands, Clement Mugenzi, Douglas R. Powell, Nikolay N. Gerasimchuk, and Lei Yang
Cooperative halogen bonding and polarized π-stacking in the formation of coloured charge-transfer co-crystals, Chideraa I. Nwachukwu, Zachary R. Kehoe, Nathan P. Bowling, Erin D. Speetzen, and Eric Bosch
Characterization of a Liquid Crystal Stabilized Pharmaceutical Oil-in-Water Emulsion Optimized for Skin Delivery, Melinda J. Sutton, David W. Osborne, Kevin Dahl, Victoria Bax, and G. Alan Schick
Methyl Linoleate and Methyl Oleate Bond Dissociation Energies: Electronic Structure Fishing for Wise Crack Products, Zachary R. Wilson and Matthew R. Siebert
Submissions from 2017
Compromised Structures: Verbal Descriptions of Mechanism Diagrams, Gautam Bhattacharyya and Michael S. Harris
Synthesis and crystal structures of two purpurin derivatives: 1,4-dihydroxy-2-propoxyanthraquinone and 2-butoxy-1,4-dihydroxyanthraquinone, E. Bosch and E.N. McClain
Shortwave infrared luminescent Pt-nanowires: a mechanistic study of emission in solution and in the solid state, Carl Cheadle, Jessica Ratcliff, Mikhail Berezin, Vadim Pal'shin, Victor N. Nemykin, and Nikolay N. Gerasimchuk
Enzyme and Cancer Cell Selectivity of Nanoparticles: Inhibition of 3-D Metastatic Phenotype and Experimental Melanoma by Zinc Oxide, Robert K. DeLong; Jennifer A. Mitchell; R. Tyler Morris; Jeffrey Comer; Miranda N. Hurst; Kartik C. Ghosh; Adam Wanekaya; Miranda Mudge; Joshua J. Smith; and For complete list of authors, see publisher's website.
Investigating students' similarity judgments in organic chemistry, N. Graulich and G. Bhattacharyya
One Lump or Two? A Plurality of Pathways in Gold(III)-Catalyzed Cyclization Transforming Propargyl Acetates to a Carene-like Bicyclo[4.1.0]heptane, Jeremy M. Hines, Jesse J. Eason, and Matthew R. Siebert
Two-dimensional fluorescence difference spectroscopy of ZnO and Mg composites in the detection of physiological protein and RNA interactions, Amanda Hoffman; Xiaotong Wu; Jianjie Wang; Amanda Brodeur; Rintu Thomas; Ravindra Thakkar; Halena Hadi; Adam K. Wanekaya; Robert K. DeLong; and For complete list of authors, see publisher's website.
Carbon nanofiber modified with osmium based redox polymer for glucose sensing, Amos Mugweru, Reaz Mahmud, Kartik Ghosh, and Adam Wanekaya
C - I...N and C - I...π halogen bonding in the structures of 1-benzyliodoimidazole derivatives, Chideraa I. Nwachukwu, Nathan P. Bowling, and Eric Bosch
Unexpected beauty and diversity in the structures of three homologous 4,5-dialkoxy-1-ethynyl-2-nitrobenzenes: The subtle interplay between intermolecular C - H...O hydrogen bonds and alkyl chain length, Shalisa M. Oburn and Eric Bosch
Zinc Complexes with Cyanoxime: Structural, Spectroscopic, and Catalysis Studies in the Pivaloylcyanoxime-Zn System, Adedamola A. Opalade, Anirban Karmakar, G. M.D.M. Rúbio, Armando J.L. Pombeiro, and Nikolay Gerasimchuk
Enhanced Electrogenerated Chemiluminescence of ruthenium and iridium coordination compounds using melatonin, Sarah Roughton and Mark M. Richter
Boot Camp To Improve Student Perception and Performance in Sophomore Organic Chemistry? Hoorah!, Matthew R. Siebert, Todd E. Daniel, and Brian D. High
Influence of CNTRENE ® C100LM carbon nanotube material on the growth and regulation of Escherichia coli, Brittany Twibell, Kalie Somerville, Geoffrey Manani, Molly Duszynski, Adam Wanekaya, and Paul Schweiger
Comparing Strong and Weak Halogen Bonding in Solution: 13C NMR, UV/Vis, Crystallographic, and Computational Studies of an Intramolecular Model, Danielle L. Widner; Emily R. Robinson; Alejandra B. Perez; Herh G. Vang; Rachel A. Thorson; Zakarias L. Driscoll; Sierra M. Giebel; Calvin W. Berndt; Eric Bosch; and For complete list of authors, see publisher's website.
Submissions from 2016
First π-linker featuring mercapto and isocyano anchoring groups within the same molecule: synthesis, heterobimetallic complexation and self-assembly on Au(111), Jason C. Applegate, Monisola K. Okeowo, Nathan R. Erickson, Brad M. Neal, Cindy L. Berrie, Nikolay N. Gerasimchuk, and Mikhail V. Barybin
Anticancer, biophysical and computational investigations of half-sandwich ruthenium(II) thiosemicarbazone complexes: The effect of arene versus thiacrown face-cap, Floyd A. Beckford; Alyssa Stott; P. Canisus Mbarushimana; Marc-Andre LeBlanc; Kinsey Hall; Samatha Smith; Jimmie L. Bullock; Nikolay N. Gerasimchuk; For complete list of authors, see publisher's website.; and For complete list of authors, see publisher's website.
X-ray Structures of 1-Ethynyl-2-Nitrobenzene and 1-Ethynyl-4,5-Dimethyl-2-Nitrobenzene: Correlation to the Enhanced Rate of Hydration and Investigation of the C-H···O Alkyne-Nitro Hydrogen Bonding, Eric Bosch and Laura Jeffries
Synthesis of Cd-free InP/ZnS Quantum Dots Suitable for Biomedical Applications, Matthew A. Ellis, Giovana Grandinetti, and Katye M. Fichter
[Fe-Fe] hydrogenase models: Iron(I)-carbonyl clusters coupled to alpha- and para-toluenethiolate ligands, Adrian L. Haleya, Lauren N. Broadbent, Lindsey S. McDaniel, Skye T. Heckman, Carlee H. Hinkle, Nikolay N. Gerasimchuk, John C. Hershberger, and Charles A. Mebi
Temperature-dependent shape-responsive fluorescent nanospheres for image-guided drug delivery, Shawn He, George Toukrakis, Oleg Berezin, Nikolay N. Gerasimchuk, Hairong Zhang, Haiying Zhou, Asaf Izraely, Walter J. Akers, and Mikhail Y. Berezin
Cations or Radicals? Inherent Reactivity of Biosynthetic Intermediates in the B-Ring Formation of Rotenoid Natural Products, Adam K. Kirkpatrick and Matthew R. Siebert
New non-aggregating bivalent cis-ML2 (M = Pd, Pt; L = pivaloylcyanoxime), Alexandra Mann, Nikolay Gerasimchuk, and Svitlana Silchenko
A 1-D coordination polymer route to catalytically active Co@C nanoparticles, Anand Pariyar, Siddharth Gopalakrishnan, Joseph Stansbery, Rajankumar R. Patel, Xinhua Liang, Nikolay N. Gerasimchuk, and Amitava Choudhurya
An Fe-S cluster in the conserved Cys-rich region in the catalytic subunit of FAD-dependent dehydrogenase complexes, Masaki Shiota, Tomohiko Yamazaki, Keiichi Yoshimatsu, Katsuhiro Kojima, Wakako Tsugawa, Stefano Ferri, and Koji Sode
Initial Report on Molecular and Electronic Structure of Spherical Multiferrocenyl/tin(IV) (Hydr)oxide [(FcSn)12O14(OH)6]X2 Clusters, Pavlo V. Solntsev, Derrick R. Anderson, Hannah M. Rhoda, Rodion V. Belosludov, Mahtab Fathi-Rasekh, Eranda Maligaspe, Nikolay N. Gerasimchuk, and Victor N. Nemykin
Conjugated, trans-Spanning Ligands as Models for Multivalent p-Phenyleneethynylenes, Herh G. Vang, Zakarias L. Driscoll, Emily R. Robinson, Casey E. Green, Eric Bosch, and Nathan Bowling
Enhanced electrogenerated chemiluminescence of Ru(bpy)32+/TPrA (bpy=2,2'-bipyridine; TPrA=tri-n-propylamine) via oxygen quenching using melatonin, Maria D. Witt, Sarah Roughton, Timothy J. Isakson, and Mark M. Richter
Carbon Nanomaterials Alter Global Gene Expression Profiles, Sara Woodman, John C.W. Short, Hyoeun McDermott, Linan Alexander, Katelyn Bartlett, Shiva Kumar Goud Gadila, Katie Schmelzle, Adam Wanekaya, and Kyoungtae Kim
Submissions from 2015
The Power of Nonconventional Phenyl C--H...N Hydrogen Bonds: Supportive Crystal-Packing Force and Dominant Supramolecular Engineering Force, Eric Bosch, Nathan P. Bowling, and Jeffrey Darko
Synthesis, characterization, and applications of poly(ethylene glycol)-block-poly(ether-sulfide) dendrimers, Wesley Dowler, Jacob Robison, Jonathan Fury, Xiaozheng Dou, Robert Delong, and Reza Sedaghat-Herati
Structural Peculiarities of Cyanoximes and their Anions: Co-crystallization of Two Diastereomers and Formation of Acid-salts, Nikolay N. Gerasimchuk, Ilia Guzai, and Pal Sipos
Extended Self-complementary Halogen Bonded Dimers, Lisa M. Kirchner, Nathan P. Bowling, and Eric Bosch
