Title

Morphology of hydrothermally synthesized ZnO nanoparticles tethered to carbon nanotubes affects electrocatalytic activity for H 2 O 2 detection

Document Type

Article

Publication Date

2013

Abstract

We describe the synthesis of zinc oxide (ZnO) nanoparticles and demonstrate their attachment to multiwalled carbon tubes, resulting in a composite with a unique synergistic effect. Morphology and size of ZnO nanostructures were controlled using hydrothermal synthesis, varying the hydrothermal treatment temperature, prior to attachment to carboxylic acid functionalized multi-walled carbon nanotubes for sensing applications. A strong dependence of electrocatalytic activity on nanosized ZnO shape was shown. High activity for H2O2 reduction was achieved when nanocomposite precursors with a roughly semi-spherical morphology (no needle-like particles present) formed at 90 °C. A 2.4-fold increase in cyclic voltammetry current accompanied by decrease in overpotential from the composites made from the nanosized, needle-like-free ZnO shapes was observed as compared to those composites produced from needle-like shaped ZnO. Electrocatalytic activity varied with pH, maximizing at pH 7.4. A stable, linear response for H2O2 concentrations was observed in the 1"“20 mM concentration range.

Recommended Citation

Wayu, Mulugeta B., Ryan T. Spidle, Tuphan Devkota, Anup K. Deb, Robert K. Delong, Kartik C. Ghosh, Adam K. Wanekaya, and Charles C. Chusuei. Morphology of hydrothermally synthesized ZnO nanoparticles tethered to carbon nanotubes affects electrocatalytic activity for H 2 O 2 detection." Electrochimica acta 97 (2013): 99-104."

DOI for the article

http://dx.doi.org/10.1016/j.electacta.2013.02.028

Department

Biomedical Sciences

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