Title

1D polymeric platinum cyanoximate: a strategy toward luminescence in the near-infrared region beyond 1000 nm

Abstract

The dark-green complex Pt(DECO)2 of PtII with a new cyanoxime ligand, 2-cyano-2-oximino-N,N′-diethylaminoacetamide, self-assembles into 1D stacks held by metallophillic interactions. The formed polymer demonstrates unique optical characteristics, showing broad absorption at ∼400−900 nm and pronounced near-infrared luminescence at 1000−1100 nm in the solid state. This finding opens a way of preparation of a new class of 1D polymeric metal complexes with emission beyond 1000 nm.

Department(s)

Chemistry

Document Type

Article

DOI

https://doi.org/10.1021/ic502805h

Publication Date

2015

Journal Title

Inorganic chemistry

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