Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: Non-chelating extended ionisable building block ligands for new MOFs

Authors

Scott Curtis, MSU Graduate Student
Olesya Ilkun, MSU Undergraduate
Amy Brown, MSU Graduate Student
Svitlana Silchenko, Missouri State University
Nikolay Gerasimchuk, Missouri State UniversityFollow

Abstract

Two new isomeric bis-cyanoximes were synthesized and characterized by a variety of spectroscopic methods including UV-visible, infrared, NMR, pK a measurements and X-ray analysis. These synthesized compounds represent the first non-chelating bis-cyanoximes that can function as building blocks for new MOF-like structures.

Department(s)

Chemistry and Biochemistry

Document Type

Article

DOI

https://doi.org/10.1039/c2ce26395e

Publication Date

1-7-2013

Recommended Citation

Curtis, Scott, Olesya Ilkun, Amy Brown, Svitlana Silchenko, and Nikolay Gerasimchuk. "Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs." CrystEngComm 15, no. 1 (2013): 152-159.

Journal Title

CrystEngComm