Title

Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin

Abstract

Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(iv) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.

Department(s)

Chemistry

Document Type

Article

DOI

https://doi.org/10.1039/c0cc02171g

Publication Date

9-21-2010

Journal Title

Chemical Communications

Share

COinS