Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin
Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(iv) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.
Solntsev, Pavlo V., Jared R. Sabin, Samantha J. Dammer, Nikolay N. Gerasimchuk, and Victor N. Nemykin. "Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin." Chemical communications 46, no. 35 (2010): 6581-6583.