Phase-Transfer Catalysis by Poly(ethylene glycol)s of β-Thioethyl Chloride Reactions

Authors

J. Milton Harris
M. Steven Paley
Reza Sedaghat-Herati Sedaghat-HeratiFollow
Samuel P. McManus

Abstract

Neighboring sulfur participation is a facile process for β-thioethyl derivatives. In the present work we examine the ability of phase-transfer catalysis by poly(ethylene glycol)s to make direct substitution, elimination, and oxidation competitive with neighboring sulfur participation for reaction of mustard chlorohydrin (1).

Document Type

Article

DOI

https://doi.org/10.1021/jo00225a048

Publication Date

1-1-1985

Recommended Citation

Harris, J. Milton, M. Steven Paley, M. R. Sedaghat-Herati, and Samuel P. McManus. "Phase-transfer catalysis by poly (ethylene glycol) s of. beta.-thioethyl chloride reactions." The Journal of Organic Chemistry 50, no. 25 (1985): 5230-5233.

Journal Title

Journal of Organic Chemistry