Title

Preparation, IR and X-Ray Crystal Structure Studies of Tl(I)-2-pyridyl-cyanoxime Complex

Abstract

The thallium(I)-2-pyridyl-cyanoxime complex was prepared in a 82% yield. An X-ray crystallography study of C7H4N3OTl (Space group P21/c, α = 4.134(1), b = 8.875(2), c = 22.217(6) Å,β = 92.55(2)°, Z = 4, R = 4.36%, wR = 3.94% for 930 reflections) showed that the complex contains thallium(I) in a trigonal bipyramidal arrangement.

Document Type

Article

DOI

https://doi.org/10.1515/znb-1992-1216

Keywords

Thallium(I)-2-pyridyl-cyanoxime Complex, X-Ray

Publication Date

12-1-1992

Journal Title

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

Share

COinS