Title

Charge-transfer absorption of olefins with nitrosonium. structural relevance to the dimethylbutene complex with dinitrogen tetraoxide

Abstract

The transient electron donor-acceptor (EDA) complexes of various olefins (dimethylbutene, etc.) with the nitrosonium acceptor (NO+) show diagnostic charge-transfer absorption bands in dichloromethane solutions at low temperatures. Since the same charge-transfer absorption bands are observed when olefins are exposed to dinitrogen tetraoxide, they are ascribed to analogous EDA complexes [olefin, NO+] NO3- that are derived from the ionic disproportionation of nitrogen dioxide.

Document Type

Article

DOI

https://doi.org/10.1163/156856796X00412

Publication Date

1-1-1996

Journal Title

Research on Chemical Intermediates

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