Electron-transfer catalysis of olefin epoxidation with nitrogen dioxide (dinitrogen tetroxide)

Abstract

The novel epoxidation of diadamantylidene 1 and related hindered olefins with NO2 proceeds by way of the cation radical 1+. generated during the electron-transfer chain (ETC) catalysis initiated by nitrosonium.

Document Type

Article

DOI

https://doi.org/10.1039/C39930000667

Publication Date

12-1-1993

Journal Title

Journal of the Chemical Society, Chemical Communications

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