Crystal structures of the coordination polymers formed between 1,2-bis(3′-pyridyl)ethyne and silver(I) trifluoromethanesulfonate
The reaction of 1,2-bis(3′-pyridyl)ethyne with silver(I) trifluoromethanesulfonate yields two coordination networks. A one-dimensional double-stranded coordination polymer was formed in acetonitrile. The silver has a square-planar coordination geometry with weak coordination to one acetonitrile molecule and the triflate counter ion. The second network, formed in dichloromethane, is a complex three-dimensional network of interconnected one-dimensional zig-zag ribbons.
Chemistry and Biochemistry
silver(I), boordination polymer, 1, 2-bis(3′-pyridyl)ethyne
Bosch, Eric, and Charles L. Barnes. "Crystal structures of the coordination polymers formed between 1, 2-bis (3′-pyridyl) ethyne and silver (I) trifluoromethanesulfonate." Journal of Coordination Chemistry 58, no. 12 (2005): 1021-1027.
Journal of Coordination Chemistry