Title

Crystal structures of the coordination polymers formed between 1,2-bis(3′-pyridyl)ethyne and silver(I) trifluoromethanesulfonate

Abstract

The reaction of 1,2-bis(3′-pyridyl)ethyne with silver(I) trifluoromethanesulfonate yields two coordination networks. A one-dimensional double-stranded coordination polymer was formed in acetonitrile. The silver has a square-planar coordination geometry with weak coordination to one acetonitrile molecule and the triflate counter ion. The second network, formed in dichloromethane, is a complex three-dimensional network of interconnected one-dimensional zig-zag ribbons.

Department(s)

Chemistry

Document Type

Article

DOI

https://doi.org/10.1080/00958970500092768

Keywords

silver(I), boordination polymer, 1, 2-bis(3′-pyridyl)ethyne

Publication Date

2005

Journal Title

Journal of Coordination Chemistry

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