Diffusion motions in hydrated sodium alginate by QENS
QENS experiments are very suitable for the study of water-polysaccharides systems both for slow polymer chains dynamics as well as for faster solvent molecules dynamics. By a suitable choice of experimental conditions as well as a properly data processing we can get information about the motion modes of various molecular groups of polymer chains m aqueous solutions presumes. Virtually we can distinguish the polymer protons motions at nanosecond time scale by choosing a narrow energy resolution window. The present work presents the QENS measurements performed at LLB, MIBEMOL neutron spectrometer on sodium alginate hydrated samples. The experimental spectra were fitted using one lorentzian fit. At high polymer concentration the quasielastic part of the line is given by the translational-rotational diffusion performed by heavy water molecules in confined spaces created by the polymer coils. The experimental data are well described by Chudley Elliot and Hall-Ross models.
Neutron scattering, Polysaccharides
Tripadus, V., J. M. Zanotti, M. Statescu, S. Mitra, D. Aranghel, M. Gugiu, M. Petre, and I. Precup. "Diffusion motions in hydrated sodium alginate by QENS." In AIP Conference Proceedings, vol. 1203, no. 1, pp. 1007-1012. American Institute of Physics, 2010.
AIP Conference Proceedings