Ion induced structures and electrical conduction in implanted polymer films

Abstract

A conducting-grain picture is presented, based on the idea that the ion-polymer interaction process can be simply described as a rapid dissipation of the thermal energy converted from the kinetic energy in the ion track region. Thermal dissipation and efficiency through electronic ionization and nuclear collisions are quite different. A critical transient temperature, determined by the critical energy deposition density, is necessary to activate a thermodynamic relaxation process along the ion track creating conducting graphitic grains. Our high resolution temperature-dependent dc conductivity data reveal a two component conductivity that depends on both one-dimensional variable-range hopping (VRH) and three-dimensional VRH. The relative importance of 3-D VRH conductivity over the entire conductivity seems to depend on the relative rate of the ion energy loss through electronic ionization processes. © 1993.

Department(s)

Physics, Astronomy, and Materials Science

Document Type

Article

DOI

https://doi.org/10.1016/0168-583X(93)95437-A

Publication Date

6-2-1993

Journal Title

Nuclear Inst. and Methods in Physics Research, B

Share

COinS