An in situ X-ray spectroscopic study of Mo6+ speciation in supercritical aqueous solutions
Abstract
In situ XRF and Mo K-edge XAS measurements were made on the ID20-B beam line at the APS on MoO3 in 1 M H2O2 aqueous solution, at temperatures between 400 and 600 °C. The samples were analyzed using a modified Bassett-type hydrothermal diamond anvil cell. Our XRF measurements show that MoO3 is highly soluble in the supercritical H2O2 aqueous fluid. Analysis of XAS spectra shows that the Mo6+ ion exhibits consistent speciation in the H2O2 aqueous solution at temperatures ranging from 400 to 600 °C.
Department(s)
Physics, Astronomy, and Materials Science
Document Type
Article
DOI
https://doi.org/10.1016/j.nima.2010.11.067
Keywords
XAS, XRF, supercritical aqueous solutions, HDAC
Publication Date
2011
Recommended Citation
Yan, Hao, Robert A. Mayanovic, Alan J. Anderson, and Peter R. Meredith. "An in situ X-ray spectroscopic study of Mo6+ speciation in supercritical aqueous solutions." Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 649, no. 1 (2011): 207-209.
Journal Title
Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment
