Electron-transfer catalysis of olefin epoxidation with nitrogen dioxide (dinitrogen tetroxide)

Authors

Eric BoschFollow
Jay K. Kochi

Abstract

The novel epoxidation of diadamantylidene 1 and related hindered olefins with NO2 proceeds by way of the cation radical 1+. generated during the electron-transfer chain (ETC) catalysis initiated by nitrosonium.

Document Type

Article

DOI

https://doi.org/10.1039/C39930000667

Publication Date

12-1-1993

Recommended Citation

Bosch, Eric, and Jay K. Kochi. "Electron-transfer catalysis of olefin epoxidation with nitrogen dioxide (dinitrogen tetroxide)." Journal of the Chemical Society, Chemical Communications 8 (1993): 667-668.

Journal Title

Journal of the Chemical Society, Chemical Communications