fac-mer Equilibrium in Solutions of VCl3in Acetonitrile¹

Authors

James F. O'Brien, Missouri State UniversityFollow

Abstract

Both the equivalent conductivity and the proton NMR spectra of solutions of vanadium trichloride in acetonitrile indicate the presence of a second species above 50 °C. The maximum value found for the equivalent conductivity, 6.21 cm2mol-1Ω-1at 76 °C, is too low for a 1:1 electrolyte. The two species present are very likely the fac and mer isomers of VC13.3CH3CN. © 1987, American Chemical Society. All rights reserved.

Department(s)

Chemistry and Biochemistry

Document Type

Article

DOI

https://doi.org/10.1021/ic00267a010

Publication Date

10-1-1987

Recommended Citation

O'Brien, J. F. "fac-mer Equilibrium in solution of vanadium trichloride in acetonitrile." Inorganic Chemistry 26, no. 20 (1987): 3264-3266.

Journal Title

Inorganic Chemistry