Solvation of tetraphenylphosphonium dicyanamide

Abstract

NMR and IR spectroscopy have been used to study the solvation of the dicyanamide ion in solvents with different chemical natures. The occurrence of two kinds of interaction of the N(CN)2−ion with the solvents has been established: by means of hydrogen bonds (alcohols, chloroform) and by ion-dipole interaction (aprotic solvents).

Document Type

Article

DOI

https://doi.org/10.1007/bf00534566

Keywords

hydrogen, alcohol, spectroscopy, hydrogen bond, chloroform

Publication Date

1988

Journal Title

Theoretical and Experimental Chemistry

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