Preparation, IR and X-Ray Crystal Structure Studies of Tl(I)-2-pyridyl-cyanoxime Complex
Abstract
The thallium(I)-2-pyridyl-cyanoxime complex was prepared in a 82% yield. An X-ray crystallography study of C7H4N3OTl (Space group P21/c, α = 4.134(1), b = 8.875(2), c = 22.217(6) Å,β = 92.55(2)°, Z = 4, R = 4.36%, wR = 3.94% for 930 reflections) showed that the complex contains thallium(I) in a trigonal bipyramidal arrangement.
Document Type
Article
DOI
https://doi.org/10.1515/znb-1992-1216
Keywords
Thallium(I)-2-pyridyl-cyanoxime Complex, X-Ray
Publication Date
12-1-1992
Recommended Citation
Gerasimchuk, N. Nikolay, Laszlo Nagy, H-G. Schmidt, Mathias Noltemeyer, Rakesh Bohra, and Herbert W. Roesky. "Preparation, IR and x-ray crystal structure studies of Tl (I)-2-pyridyl-cyanoxime complex." Zeitschrift für Naturforschung B 47, no. 12 (1992): 1741-1745.
Journal Title
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
