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Submissions from 2015

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Intramolecular Halogen Bonding in Solution: 15N, 13C, and 19F NMR Studies of Temperature and Solvent Effects, Rachel A. Thorson, Garrett R. Woller, Zakarias L. Driscoll, Brooke E. Geiger, Crystal A. Moss, Ashley L. Schlapper, Erin D. Speetzen, Eric Bosch, Mate Erdelyi, and Nathan Bolwing

Classic Isomeric 1, 2-and 2, 1-nitrosonaphthols are Oximes in Solid State and Solutions, Sergiy I. Tyukhtenko, Michael Hilton, and Nikolay N. Gerasimchuk

Submissions from 2014

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Probing the interaction at the nano-bio interface using raman spectroscopy: ZnO nanoparticles and adenosine triphosphate biomolecules, A. Bhaumik, A. M. Shearin, Robert K. Delong, Adam K. Wanekaya, and Kartik C. Ghosh

Two-and Four-Year Institutional Collaborations to Educate Engaged Citizens, Steve Bishop, John D. Bookstaver, Gloria J. Galanes, Tamera S. Jahnke, and Victor Matthews

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Comparison of sp-C-H...N Hydrogen Bond Lengths in Fluorinated and Nonfluorinated Ethynylbenzenes, Eric Bosch

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Structural Analysis of Methyl-Substituted Nitrosobenzenes and Nitrosoanisoles, Eric Bosch

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Interaction of YOYO-1 with guanine-rich DNA, Shohini Ghosh Datta, Christopher Reynolds, Yugender K. Goud, and Bhaskar Datta

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Synthesis, Properties, and Applications of Light-Insensitive Silver (I) Cyanoximates, Nikolay Gerasimchuk

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Synthesis and characterization of two cyanoxime ligands, their precursors, and light insensitive antimicrobial silver(I) cyanoximates, Courtney N. Riddles, Mark Whited, Shalaka R. Lotlikar, Korey Still, Marianna Patrauchan, Svitlana Silchenko, and Nikolay Gerasimchuk

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Electrogenerated Chemiluminescence of tris(2-phenylpyridine)iridium(III) in Water, Acetonitrile and Trifluoroethanol, Wesley D. Robinson and Mark M. Richter

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Electrochemical method for analysis of cholesterol based on in situ synthesized graphene decorated with zinc oxide nanoparticles, Elli Watanabe, Ryan T. Spidle, Steven Caudle, Geoffrey Manani, Adam K. Wanekaya, and Amos Mugweru

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Intramolecular Halogen Bonding Supported by an Aryldiyne Linker, Danielle L. Widner, Qianwei R. Knauf, Mark T. Merucci, Thomas R. Fritz, Jon S. Sauer, Erin D. Speetzen, Eric Bosch, and Nathan P. Bowling

Submissions from 2013

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Extrapolation from small molecules to polymers: A simple and effective way to promote interest in both organic chemistry and polymer chemistry, Eric Bosch

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Serendipity and the Search for Short N---I Halogen Bonds, Eric Bosch

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The first bis-cyanoxime: Synthesis and properties of a new versatile and accessible polydentate bifunctional building block for coordination and supramolecular chemistry, Carl Cheadle, Nikolay Gerasimchuk, Charles L. Barnes, Sergiy I. Tyukhtenko, and Svitlana Silchenko

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Aqueous red-emitting silicon nanoparticles for cellular imaging: Consequences of protecting against surface passivation by hydroxide and water for stable red emission, Sheng-Kuei Chiu, Beth A. Manhat, William J.I. DeBenedetti, Anna L. Brown, Katye Fichter, Tania Vu, Micah Eastman, Jun Jiao, and Andrea M. Goforth

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Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: Non-chelating extended ionisable building block ligands for new MOFs, Scott Curtis, Olesya Ilkun, Amy Brown, Svitlana Silchenko, and Nikolay Gerasimchuk

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Structural influences impacting the role of the 9-ylidene bond in the electronic tuning of structures built upon 9-fluorenylidene scaffolds, Galen L. Eakins, Matthew W. Cooper, Nikolay N. Gerasimchuk, Terry J. Phillips, Bryan E. Breyfogle, and Chad J. Stearman

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Polymeric nanofibers for the removal of Cr(III) from tannery waste water, Iman Y. El-Sheriff, Sagar B. Tolani, Kennedy Ofosu, Ola A. Mohamed, and Adam K. Wanekaya

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Synthesis and self-assembly of New Poly(ethylene glycol)-block-poly(ester- sulfide) dendrimers, Jonathan J. Fury, Jacob Robison, and Reza Sedaghat-Herati Sedaghat-Herati

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Sodium-centered dodecanuclear Co (II) and Ni (II) complexes with 2-(phosphonomethylamino) succinic acid: Studies of spectroscopic, structural, and magnetic properties, Andriy Gudima, Ganna Shovkova, Olena Trunova, Fernande Grandjean, Gary Long, and Nikolay Gerasimchuk

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Conjugated metallorganic macrocycles: opportunities for coordination-driven planarization of bidentate, pyridine-based ligands, Danielle C. Hamm; Lindsey A. Braun; Alex N. Burazin; Amanda M. Gauthier; Kendra O. Ness; Casey E. Biebel; Jon S. Sauer; Robin Tanke; Eric Bosch; and For complete list of authors, see publisher's website.

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Synthesis, properties and crystal structure of the 2,4-dichlorophenyl- cyanoxime: A powerful carbonyl reductase inhibitor, Michael Hilton, Nikolay N. Gerasimchuk, Svitlana Silchenko, and Henry A. Charlier

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Glucose Determination in Beverages Using Carbon Nanotube Modified Biosensor: An Experiment for the Undergraduate Laboratory, J. Mark Hobbs, Niral N. Patel, Daniel W. Kim, Joseph K. Rugutt, and Adam K. Wanekaya

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Electrocatalytic oxidation of propranol using microwave synthesized graphene decorated with gold nanoparticles and single walled carbon nanotubes, Geoffrey Manani, Matthew Morris, Steven Caudle, Adam K. Wanekaya, and Amos Mugweru

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Synthesis and characterization of Co(iii) amidoamine complexes: Influence of substituents of the ligand on catalytic cyclic carbonate synthesis from epoxide and carbon dioxide, Punnamchandar Ramidi, Nikolay N. Gerasimchuk, Yashraj Gartia, Charlette M. Felton, and Anindya Ghosh

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MPEG-PAMAM-G4 nucleic acid nanocomplexes: Enhanced stability, rnase protection, and activity of splice switching oligomer and poly I:C RNA, Juan Reyes-Reveles; Reza Sedaghat-Herati; David R. Gilley; Ashley M. Schaeffer; Kartik C. Ghosh; Thomas D. Greene; Hannah E. Gann; Wesley A. Dowler; Stephen Kramer; and For complete list of authors, see publisher's website.

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Geochemical sequestration reactions within the Lamotte Sandstone at five different locations in Missouri, Nelson Rono, Richard N. Biagioni, Charles W. Rovey, and Melida Gutierrez

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Dual control of the selectivity in the formal nucleophilic substitution of bromocyclopropanes en route to densely functionalized, chirally rich cyclopropyl derivatives, Pavel Ryabchuk, Andrew Edwards, Nikolay Gerasimchuk, Marina Rubina, and Michael Rubin

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Organics in a Hanford mixed waste revisited: Myriad organics and chelator fragments unmasked, Anthony P. Toste, T. J. Lechner-Fish, and R. D. Scheele

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Direct Dynamics Simulations of the Product Channels and Atomistic Mechanisms for the OH- + CH3I Reaction. Comparison with Experiment, Jing Xie, Rui Sun, Matthew R. Siebert, Rico Otto, Roland Wester, and William L. Hase

Submissions from 2012

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Dendrimers Bind Antioxidant Polyphenols and cis-Platin drug, Amine Abderrezak, Philippe Bourassa, Jean-Sebastian Mandeville, Reza Sedaghat-Herati, and Heidar-Ali Tajmir-Riahi

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Coordination Network Formed Between 5,5′-Bipyrimidine and Copper(I) Iodide, Eric Bosch

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Synthesis of 1,2-Bis(8′-quinolinyl)ethyne and X-ray Characterization of Its Rearranged Oxidation Product 2-Quinoline-8-yl-pyrrolo[3,2,1-ij]quinoline-4-one, Eric Bosch, Charles L. Barnes, Michael Stutelberg, and Barrett Eichler

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DNA template-assisted modulation of horseradish peroxidase activity, Shohini Ghosh Datta, Xiaozheng Dou, Alyxandria Shibley, and Bhaskar Datta

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Polymeric Nucleic Acid Vehicles Exploit Active Interorganelle Trafficking Mechanisms, Katye M. Fichter, Nilesh P. Ingle, Patrick M. McLendon, and Theresa M. Reineke

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Structure and magnetic properties of co-doped ZnO dilute magnetic semiconductors synthesized via hydrothermal method, Kartik C. Ghosh, Pawan K. Kahol, S Bhamidipati, N Das, and S. Khanra

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Electrogenerated Chemiluminescence Quenching of Ru(bpy)32+ (bpy = 2,2'-bipyridine) in the presence of Acetaminophen, Salicylic Acid and their metabolites, Catherine S. Haslag and Mark M. Richter

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Evidence for involvement of medium chain acyl-CoA dehydrogenase in the metabolism of phenylbutyrate, Kaitlyn Kormanik, Heejung Kang, Dean Cuebas, Jerry Vockley, and Al Walid Mohsen

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Synthesis, Characterization, and studies of coordination-polymeres with isomeric pyridylcyanoximes: Route to metal ribbons with very short Tl•••Tl separations, Daniela Marcano, Nikolay Gerasimchuk, Victor Nemykin, and Svitlana Silchenko

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Reaction Dynamics of Temperature-Variable Anion Water Clusters Studied with Crossed Beams and by Direct Dynamics, R Otto, J Xie, J Brox, S Trippel, M. Stei, T Best, M. Siebert, W. L. Hase, and R. Wester

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Part 2: In vitro cytotoxicity studies of two ML 2 complexes (M = Pd, Pt; L = 2-cyano-2-isonitroso-N-morpholylacetamide, HMCO, Jessica Ratcliff, Paul Durham, Michael Keck, Andriy Mokhir, and Nikolay Gerasimchuk

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Part 1: Experimental and theoretical studies of 2-cyano-2-isonitroso-N- piperidynylacetamide (HPiPCO), 2-cyano-2-isonitroso-N-morpholylacetamide (HMCO) and their Pt- and Pd-complexes, Jessica Ratcliff, Janina Kuduk-Jaworska, Henryk Chojnacki, Victor Nemykin, and Nikolay Gerasimchuk

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Nucleic-acid-binding chromophores as efficient indicators of aptamer-target interactions, Kwabena Sarpong and Bhaskar Datta

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Potential Energy Surface for C2 H4 I+ Dissociation Including Spin-Orbit Effects, Matthew R. Siebert, Adelia J. A. Aquino, Wibe A. De Jong, Giovanni Granucci, and William L. Hase

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Gas-Phase Chemical Dynamics Simulations on the Bifurcating Pathway of the Pimaradienyl Cation Rearrangement: Role of Enzymatic Steering in Abietic Acid Biosynthesis, Matthew R. Siebert, Paranjothy Manikandan, Rui Sun, Dean J. Tantillo, and William L. Hase

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Chemiluminescence from osmium(ii) complexes with phenanthroline, diphosphine and diarsine ligands, Elizabeth M. Zammit, Gregory J. Barbante, Brenden Carlson, Egan H. Doeven, Neil W. Barnett, Conor F. Hogan, Mark M. Richter, and Paul S. Francis

Submissions from 2011

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Design and Synthesis of C2-Symmetric N-Heterocyclic Carbene Precursors and Metal Carbenoids, Abigail Albright, Daniel Eddings, Regina Black, Christopher J. Welch, Nikolay N. Gerasimchuk, and Robert E. Gawley

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Effects of nanomaterials on luciferase with significant protection and increased enzyme activity observed for zinc oxide nanomaterials, S. Barber; M. Abdelhakiem; Kartik C. Ghosh; R. Spidle; B. Jacobs; L. Washington; J. Li; Adam K. Wanekaya; Robert K. DeLong; and For complete list of authors, see publisher's website.

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Half-sandwich ruthenium-arene complexes with thiosemicarbazones: Synthesis and biological evaluation of [(η6-p-cymene)Ru(piperonal thiosemicarbazones)Cl]Cl complexes, Floyd Beckford, Deidra Dourth, Michael Shaloski Jr., Jacob Didion, Jeffrey Thessing, Jason Woods, Vernon Crowell, Nikolay Gerasimchuk, Antonio Gonzalez-Sarrias, and Navindra P. Seeram

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Synthesis and structure of [(η6-p-cymene)Ru(2-anthracen-9- ylmethylene-N-ethylhydrazinecarbothioamide)Cl]Cl; Biological evaluation, topoisomerase II inhibition and reaction with DNA and human serum albumin, Floyd Beckford, Jeffrey Thessing, Jason Woods, Jacob Didion, Nikolay Gerasimchuk, Antonio Gonzalez-Sarrias, and Navindra P. Seeram

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Role of counterions in the structures of diquinolinyl-silver coordination polymers, Eric Bosch, Julie Matheny, Amy E. Brown, and Barrett Eichler

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Tuning HOMO-LUMO levels: Trends leading to the design of 9-fluorenone scaffolds with predictable electronic and optoelectronic properties, Galen L. Eakins, Joshua S. Alford, Brandon J. Tiegs, Bryan E. Breyfogle, and Chad J. Stearman

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An Excursion into the Intriguing World of Polymeric Tl(I) and Ag(I) Cyanoximates, Nikolay Gerasimchuk

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Looking ahead: Challenges and opportunities in organometallic chemistry, Simon J. Higgins, Richard J. Nichols, Santiago Martin, Pilar Cea, Herre S. J. Van Der Zant, Mark M. Richter, and Paul J. Low

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Computational Prediction of 1 H and 13 C Chemical Shifts: A Useful Tool for Natural Product, Mechanistic and Synthetic Organic Chemistry, Michael W. Lodewyk, Matthew R. Siebert, and Dean J. Tantillo

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Epithelial cell specificity and apotope recognition by serum autoantibodies in primary biliary cirrhosis, Guanghua Rong; Renqian Zhong; Ana Lleo; Patrick S. C. Leung; Dean A. Cuebas; Howard J. Worman; Pietro Invernizzi; Gregory J. Gores; Gary Norman; and For complete list of authors, see publisher's website.

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Ionic liquid adsorbate enhanced electrogenerated chemiluminescence of ruthenium, osmium, and iridium complexes in water, Jared Roop, Michael Nothnagel, Megan Schnuriger, Mark M. Richter, and Gary A. Baker

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Electrogenerated chemiluminescence from osmium(II) polypyridine carbonyl chloride systems, Megan Schnuriger, Mark M. Richter, and Brenden Carlson

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Electrogenerated chemiluminescence properties of bisalicylideneethylenediamino (salen) metal complexes, Megan Schnuriger, Eric Tague, and Mark M. Richter

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Synthesis, characterization, X-ray structure, and mixed-valence states of trans-dichlorotin(IV)-5,10,15,20-tetraferrocenylporphyrin, Pavlo V. Solntsev, Ben D. Neisen, Jared R. Sabin, Nikolay N. Gerasimchuk, and Victor N. Nemykin

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Applications of Nanoscale Carbon-Based Materials in Heavy Metal Sensing and Detection, Adam K. Wanekaya

Submissions from 2010

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Role of sp-C-H-N hydrogen bonding in crystal engineering, Eric Bosch

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Complexation of silver(I) cation by a series of heterosubstituted dipyridyl ligands, Nathan L. Brennan, Charles L. Barnes, and Eric Bosch

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Kinetics of G-Protein Coupled Receptor Endosomal Trafficking Pathways Revealed By Single Quantum Dots, Katye M. Fichter, Marc Flajolet, Paul Greengard, and Tania Q. Vu

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Reversible Cu4 ↔ Cu6 core interconversion and temperature induced single-crystal-to-single-crystal phase transition for copper(I) carboxylate, Alexander S. Filatov, Oleksandr Hietsoi, Yulia Sevryugina, Nikolay N. Gerasimchuk, and Marina A. Petrukhina

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Preparation, spectroscopic, and structural characterization of the first Co(III) cyanoxime complex: two polymorphs offac-,tris(benzoylcyanoximato)cobalt(III), Co(BCO)3, Nikolay Gerasimchuk, Charles L. Barnes, and David Boaz

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Light Insensitive Silver(I) Cyanoximates As Antimicrobial Agents for Indwelling Medical Devices, Nikolay Gerasimchuk, Andrzej Gamian, Garrett Glover, and Bogumila Szponar

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2-Cyano-2-isonitrosoacetamide and its Ag(i) complexes. Silver(i) cyanoximate as a non-electric gas sensor, Nikolay N. Gerasimchuk, Andrey N. Esaulenko, Kent N. Dalley, and Curtis Moore

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Spectroscopic analysis of interactions between alkylated silanes and alumina nanoporous membranes, Jonathan L. Hardin, Nathan A. Oyler, Erich D. Steinle, and Gary A. Meints

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Redox polymer covalently modified multiwalled carbon nanotube based sensors for sensitive acetaminophen and ascorbic acid detection, Nathaniel Havens, Phong Trinh, Daniel Kim, Manelich Luna, Adam K. Wanekaya, and Amos Mugweru

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Highly Sensitive and Selective Dopamine Biosensor Fabricated with Silanized Graphene, Shifeng Hou, Mark L. Kasner, Shujun Su, Krutika Patel, and Robert Cuellar

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Formation of highly stable dispersions of silane-functionalized reduced graphene oxide, Shifeng Hou, Shujun Su, Marc L. Kasner, Pratik Shah, Krutika Patel, and Clemonne John Madarang

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Solid state 2h nmr analysis of furanose ring dynamics in dna containing uracil, Monica N. Kinde-Carson, Crystal Ferguson, Nathan A. Oyler, Gerard S. Harbison, and Gary A. Meints

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Poly(glycoamidoamine) Vehicles Promote pDNA Uptake Through Multiple Routes and Efficient Gene Expression via Caveola-mediated Endocytosis, Patrick M. McLendon, Katye M. Fichter, and Theresa M. Reineke

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Serendipity in the Crystallization of a Series of C-Alkylcalix[4]resorcinarenes from Alcoholic Solvents, Aaron Alexander Momose and Eric Bosch

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Efficient electrogenerated chemiluminescence from osmium(ii) polypyridine systems containing tetraphenylarsine or diphenylphosphine ligands, Niall S. Pennington, Mark M. Richter, and Brenden Carlson

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Differentiating Mechanistic Possibilities for the Thermal, Intramolecular [2+2] Cycloaddition of Allene-ynes, Matthew R. Siebert, Joshua M. Osbourn, Kay M. Brummond, and Dean J. Tantillo

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Fundamental Properties of N-Alkenylaziridines - Implications for the Design of New Reactions and Organocatalysts, Matthew R. Siebert and Dean J. Tantillo

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Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin, Pavlo V. Solntsev, Jared R. Sabin, Samantha J. Dammer, Nikolay N. Gerasimchuk, and Victor N. Nemykin

Submissions from 2009

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Coreactant electrogenerated chemiluminescence of ruthenium porphyrins, Angela Bolin and Mark M. Richter

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Dendrimers bind human serum albumin, E. Froehlich, J. S. Mandeville, C. J. Jennings, R. Sedaghat-Herati, and H. A. Tajmir-Riahi

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Synthesis of new poly(ethylene glycol)-block-poly(ester sulfide) dendrimers, Jonathan J. Fury, Erich F. Altenhofer, and Reza Sedaghat-Herati

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Monovalent K, Cs, Tl, and Ag nitrosodicyanomethanides: Completely different 3D networks with useful properties of luminescent materials and nonelectric sensors for gases†, Garrett Glover, Nikolay Gerasimchuk, Richard Biagioni, and Konstantin V. Domasevitch

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Detection of Trace Heavy Metal Ions Using Carbon Nanotube- Modified Electrodes, Jeffrey Morton, Nathaniel Havens, Amos Mugweru, and Adam K. Wanekaya

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Conjugate Addition−Dipolar Cycloaddition Cascade for the Synthesis of Benzo[a]quinolizine and Indolo[a]quinolizine Scaffolds: Application to the Total Synthesis of (±)-Yohimbenone, Chad J. Stearman, Michael Wilson, and Albert Padwa

Submissions from 2008

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Cation-induced π-stacking, Eric Bosch, Charles L. Barnes, Nathan L. Brennan, Galen L. Eakins, and Bryan E. Breyfogle

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In-Situ Electropolymerization of DNA-Templated Aniline Assemblies on a Gold Surface Electrochemical and Solid State Letters, Wen Chen, Mira Josowicz, Bhaskar Datta, Gary B. Schuster, and Jiri Janata

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DNA-Directed Synthesis of Aniline and 4-Aminobiphenyl Oligomers: Programmed Transfer of Sequence Information to a Conjoined Polymer Nanowire, Bhaskar Datta and Gary B. Schuster

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Peptide-Functionalized Poly(ethylene glycol) Star Polymers: DNA Delivery Vehicles with Multivalent Molecular Architecture, Katye M. Fichter, Le Zhang, Kristi L. Kiick, Theresa M. Reineke, and T M. Reineke

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Alteration in prehospital drug concentration after thermal exposure, Dustin L. Gammon, Shujun Su, Roger Huckfieldt, Janet Jordan, Robert Patterson, Phillip J. Finley, and Cindy Lowe

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Synthesis and characterization of disubstituted arylcyanoximes and their several metal complexes, Nikolay Gerasimchuk, Leon Goeden, Paul L. Durham, Charles Barnes, John F. Cannon, Svitlana Silchenko, and Ismael Hidalgo

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Benz(2-heteroaryl)cyanoximes and their Tl(i) complexes: new room temperature blue emitters, Olesya T. Ilkun, Stephen J. Archibald, Charles L. Barnes, Nikolay Gerasimchuk, Richard Biagioni, Svitlana Silchenko, Olga A. Gerasimchuk, and Victor N. Nemykin

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Solid-State Nuclear Magnetic Resonance Spectroscopy Studies of Furanose Ring Dynamics in the DNAHhaI Binding Site, Gary A. Meints, Paul A. Miller, Kari Pederson, Zahra Shajani, and Gary Drobny

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Redox Protein-Polymer Films for Simultaneous Determination of Ascorbic Acid and Hydrogen Peroxide, Amos Mugweru, Hoang Khoa, Emmanuel Yawson, Sagar Tolani, and Adam Wanekaya

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Synthesis and Characterization of Two Intensely Colored Tris(benzoylcyanoxime)iron(II) Anionic Complexes, Travis Owen, Fernande Grandjean, Gary J. Long, Konstatin v. Domasevitch, and Nikolay Gerasimchuk

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Backbone dynamics in the DNA HhaI protein binding site, Kari Pederson, Gary A. Meints, Zahra Shajani, Paul A. Miller, and Gary P. Drobny

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Synthesis of 1,2- bis (2'-ethynylpyrimidyl) benzene and characterization of the coordination complexes with palladium(II) chloride and silver(I) trifluoromethanesulfonate, Nate C. Schultheiss, Joseph M. Ellsworth, Eric Bosch, and Charles L. Barnes

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[3,3]-Sigmatropic Shifts of N-Allylhydrazones: Quantum Chemical Comparison of Concerted and Radical Cation Pathways, Matthew R. Siebert and Dean J. Tantillo

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Cycloaddition/Ring Opening Reaction Sequences of N -Alkenyl Aziridines: Influence of the Aziridine Nitrogen on Stereoselectivity, Matthew R. Siebert, Andrei K. Yudin, and Dean J. Tantillo